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Summary:PURPOSE:To improve economical efficiency by supplying methanol to a catalytic combustion unit, igniting a fire, subsequently raising the temperature to >= the catch fire point of a specified lower hydrocarbon-based fuel and changing over to the lower hydrocarbon-based fuel. CONSTITUTION:Methanol and preheated air are supplied to a mixing type-vaporizer 18 for vaporization of methanol and ignition is carried out at the ordinary temperature in a catalytic combustion unit 16 containing a packed oxidizing catalyst such as Pt. At a point of time when the temperature is raised, by combustion of methanol, to >=the catch fire point of a lower hydrocarbon fuel such as natural gas or LPG incapable of catalytic combustion if the temperature is not high, the fuel line 26 is changed to the lower hydrocarbon fuel. Methanol and steam are supplied to a reforming unit 10 containing a packed reforming catalyst such as Cu and steam reforming is carried out by indirect heating using a combustion gas from the catalytic combustion unit 16. The resultant reformed gas discharged from the reforming unit 10 is supplied to a hydrogen purification unit 12 for separation and purification of hydrogen and the obtained hydrogen is taken out. An off-gas containing combustible components is stored in an off-gas tank 14 and used as a fuel for the catalytic combustion unit 16.
Bibliography:Application Number: JP19900291036