ELECTRODE FOR LITHIUM ION SECONDARY BATTERY

To provide means for improving cycle durability in a lithium ion secondary battery.SOLUTION: An electrode for a lithium ion secondary battery includes an electrode active material, and a first binder that is ionically conductive and is a fluoropolymer containing -SO3X (X is a hydrogen atom, an alkal...

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Bibliographic Details
Main Authors WATANABE MANABU, AISO YUKA, ARIHARA KAZUKI
Format Patent
LanguageEnglish
Japanese
Published 26.02.2024
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Summary:To provide means for improving cycle durability in a lithium ion secondary battery.SOLUTION: An electrode for a lithium ion secondary battery includes an electrode active material, and a first binder that is ionically conductive and is a fluoropolymer containing -SO3X (X is a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, or an ammonium group) and a second binder that is non-ionically conductive as a binder, and includes an electrode active material layer whose binder coverage ratio θBinder expressed by the following formula (1) is 70% or more. In the formula (1), SA is the BET specific surface area of the material constituting the electrode active material layer excluding the binder, SB is the BET specific surface area of the binder, and SC is the BET specific surface area of the electrode active material layer.SELECTED DRAWING: None 【課題】リチウムイオン二次電池においてサイクル耐久性を向上させうる手段を提供する。【解決手段】電極活物質と、バインダとして、イオン伝導性であり、-SO3X(Xは水素原子、アルカリ金属原子、アルカリ土類金属原子、またはアンモニウム基である)を含むフッ素系ポリマーである第1のバインダおよび非イオン伝導性である第2のバインダと、を含み、下記式(1)で表されるバインダ被覆率θBinderが70%以上である電極活物質層を含む、リチウムイオン二次電池用電極である:JPEG2024025740000009.jpg14130式(1)中、SAは、電極活物質層を構成する材料のうちバインダを除いた材料のBET比表面積であり、SBは、バインダのBET比表面積であり、SCは、電極活物質層のBET比表面積である。【選択図】なし
Bibliography:Application Number: JP20230130249