CONDUCTIVE COMPLEX, METHOD FOR PRODUCING THE SAME, AND CONDUCTIVE FILM, SENSOR, BIOLOGICAL SENSOR, FLEXIBLE DEVICE, CONDUCTIVE FABRIC, BIOELECTRODE AND WEARABLE DEVICE COMPRISING THE SAME

• Main Authors: KOBAYASHI YASUHIRO, MURASE SEIICHIRO, NAITO KOJIRO
• Format: Patent
• Language: English; Japanese
• Published: 01.07.2021
• Subjects: BASIC ELECTRIC ELEMENTS; CABLES; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; CONDUCTORS; DIAGNOSIS; ELECTRICITY; HUMAN NECESSITIES; HYGIENE; IDENTIFICATION; INSULATORS; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; MEDICAL OR VETERINARY SCIENCE; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING ORDIELECTRIC PROPERTIES; SURGERY; THEIR PREPARATION OR CHEMICAL WORKING-UP; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS

To provide a conductive complex having excellent durability against repeated electrification.SOLUTION: A conductive complex has (a) a polymer having a repeating unit represented by general formula (1), and (b) an organic phosphate compound (in the formula (1), R11 and R12 are independently selected from the group consisting of a hydrogen atom, a hydroxy group, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an alkoxy group, an alkylthio group, arylether group, an arylthioether group, an aryl group, a heteroaryl group, a heterocyclic group and a halogen atom. X is an oxygen atom, a sulfur atom, a selenium atom, or N-R13, and R13 is selected from the group consisting of a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heteroaryl group and a heterocyclic group).SELECTED DRAWING: None 【課題】繰り返し通電に対する耐久性に優れた導電性複合体を提供する。【解決手段】（ａ）下記一般式（１）で表される繰り返し単位を有する重合体、および（ｂ）有機リン酸化合物とを含有する、導電性複合体。（式（１）において、Ｒ１１およびＲ１２はそれぞれ独立に、水素原子、ヒドロキシ基、アルキル基、シクロアルキル基、アルケニル基、シクロアルケニル基、アルキニル基、アルコキシ基、アルキルチオ基、アリールエーテル基、アリールチオエーテル基、アリール基、ヘテロアリール基、複素環基およびハロゲン原子からなる群より選ばれる。Ｘは、酸素原子、硫黄原子、セレン原子、またはＮ−Ｒ１３であり、Ｒ１３は、水素原子、アルキル基、シクロアルキル基、アルケニル基、シクロアルケニル基、アルキニル基、アリール基、ヘテロアリール基および複素環基からなる群より選ばれる。）【選択図】なし