REACTIVE FLUORINE-CONTAINING SULFONYLIMIDE AND POLYMER THEREOF, AND ANTISTATIC AGENT CONTAINING THE SAME

• Main Authors: MATSUMURA NORIAKI, KAMIYA TAKESHI
• Format: Patent
• Language: English; Japanese
• Published: 31.10.2019
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; ADHESIVES; CHEMISTRY; COMPOSITIONS BASED THEREON; DYES; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; POLISHES; THEIR PREPARATION OR CHEMICAL WORKING-UP

To provide a novel compound capable of preventing bleeding out from a resin, and having excellent antistatic action, and an antistatic agent containing the same.SOLUTION: There is provided a polymer having reactive fluorine-containing sulfonylimide represented by the following general formula (1) and a repeating unit based thereon. In the general formula (1), Rrepresents a hydrogen atom, a linear or branched alkyl group having 1 to 10 carbon atoms, an alkali metal ion or an onium cation, Rrepresents a methyl group or an ethyl group, Rfrepresents a fluorine atom or a linear or branched perfluoroalkyl group having 1 to 4 carbon atoms, Rfrepresents a linear or branched perfluoroalkylene group having 1 to 4 carbon atoms, X represents a connection group which is a bivalent organic group, and Arepresents an alkali metal ion or an onium cation.SELECTED DRAWING: None 【課題】樹脂からのブリードアウトを防止でき、優れた帯電防止作用を有する新規な化合物およびこれを含有する帯電防止剤を提供する。【解決手段】下記の一般式（１）で表され反応性含フッ素スルホニルイミドおよびこれに基づく繰り返し単位を有する重合体。ただし、下記の一般式（１）において、Ｒ１は水素原子、炭素数１〜１０の直鎖状あるいは分岐状のアルキル基、アルカリ金属イオンまたはオニウムカチオンを表し、Ｒ２はメチル基またはエチル基を表し、Ｒｆ１はフッ素原子または炭素数１〜４の直鎖状あるいは分岐状のパーフルオロアルキル基を表し、Ｒｆ２は炭素数１〜４の直鎖状あるいは分岐状のパーフルオロアルキレン基を表し、Ｘは２価の有機基である連結基を表し、Ａ＋はアルカリ金属イオンまたはオニウムカチオンを表す。［化１］【選択図】なし