POROUS POLYMER METAL COMPLEX, AND GAS ABSORBENT, GAS SEPARATION DEVICE, GAS STORAGE DEVICE, CATALYST, CONDUCTIVE MATERIAL AND SENSOR USING THE SAME

• Main Authors: KAJIRO HIROSHI, KITAGAWA SUSUMU, MATSUDA RYOTARO, TOKUMARU SHINJI
• Format: Patent
• Language: English; Japanese
• Published: 31.08.2017
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; METALLURGY; ORGANIC CHEMISTRY; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; SEPARATION; THEIR RELEVANT APPARATUS; TRANSPORTING

PROBLEM TO BE SOLVED: To provide a porous polymer metal complex, and a gas absorber, a gas storage device and a gas separation device using the same and having excellent properties.SOLUTION: There is provided a porous polymer metal complex having a constitutional unit of [AXY], where A represents a transition metal ion, X represents a first ligand which is an isophthalic acid ion having a functional group containing halogen other than fluorine at the 5-position, Y represents a bipyridyl second ligand having ligand points in both terminals of the molecule and n represents the number of constitutional units consisting of AXY.SELECTED DRAWING: None 【課題】多孔性高分子金属錯体及びこれを用いた優れた特性を有するガス吸着材、ガス貯蔵装置およびガス分離装置を提供することを目的とする。【解決手段】［ＡＸＹ］n（式中、Ａは遷移金属イオンを表し、Ｘは５位にふっ素以外の含ハロゲン官能基を有するイソフタル酸イオンである第一配位子を表し、Ｙは配位点を分子の両末端に有しているビピリジル型の第二配位子を表し、ｎは、ＡＸＹから成る構成単位の数を表す）の構造単位を有する多孔性高分子金属錯体。【選択図】なし