AZEOTROPE AND AZEOTROPE-LIKE COMPOSITIONS USEFUL FOR PRODUCTION OF HALOOLEFINS

• Main Authors: RYAN HULSE, PHAM HANG T, TUNG HSUEH SUNG, KONSTANTIN A POKROVSKI, MERKEL DANIEL C
• Format: Patent
• Language: English; Japanese
• Published: 27.10.2016
• Subjects: ADHESIVES; CHEMISTRY; DYES; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; PAINTS; POLISHES

PROBLEM TO BE SOLVED: To provide new hydrofluoroolefin (HFO)-based mixtures that are acceptable and environmentally safer substitutes for CFCs, HCFCs, and HFCs, which may be used for HFO production or within one or a combination of applications such as refrigerants, blowing agents and solvents.SOLUTION: A ternary azeotrope or azeotrope-like composition consists essentially of hydrogen fluoride, 2-chloro-3,3,3-trifluoropropene, and a third component selected from the group consisting of 1,1,2,3-tetrachloropropene and 1,1,1,2,2-pentafluoropropane. In the ternary azeotropic or azeotrope-like composition, hydrogen fluoride is present in an amount from about 3.0 to about 28.0 wt.%; 2-chloro-3,3,3-trifluoropropene is present in an amount from about 68.0 to about 93.0 wt.%; and 1,1,2,3-tetrachloropropene is present in an amount from about 2.5 to about 4.3 wt.%.SELECTED DRAWING: None 【課題】ヒドロフルオロオレフィン（ＨＦＯ）を製造するため、又は冷媒、発泡剤、溶剤等の用途の１つ又は組み合わせの範囲内で用いることができる、ＣＦＣ、ＨＣＦＣ、及びＨＦＣに対する許容でき且つ環境により優しい代替物である新規なＨＦＯベースの混合物の提供。【解決手段】フッ化水素、２−クロロ−３，３，３−トリフルオロプロペン、並びに１，１，２，３−テトラクロロプロペン及び１，１，１，２，２−ペンタフルオロプロパンから選択される第３の成分から実質的に構成される３元の共沸混合物又は共沸混合物様の組成物。フッ化水素が約３．０〜約２８．０重量％の量で存在し；２−クロロ−３，３，３−トリフルオロプロペンが約６８．０〜約９３．０重量％の量で存在し；１，１，２，３−テトラクロロプロペンが約２．５〜約４．３重量％の量で存在する、３元の共沸性又は共沸混合物様の組成物。【選択図】なし