METHOD FOR PRODUCING ALKENE COMPOUND HAVING ACYLOXY GROUP AT TERMINAL

PROBLEM TO BE SOLVED: To provide a method for producing an alkene compound having an acyloxy group easily in a small number of steps and more inexpensively.SOLUTION: There is provided a method for producing a compound represented by the following general formula (1) which comprises a step of reactin...

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Bibliographic Details
Main Authors YAGI KENJI, KOMATSUKI YASUHIRO
Format Patent
LanguageEnglish
Japanese
Published 02.03.2015
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Summary:PROBLEM TO BE SOLVED: To provide a method for producing an alkene compound having an acyloxy group easily in a small number of steps and more inexpensively.SOLUTION: There is provided a method for producing a compound represented by the following general formula (1) which comprises a step of reacting an acylated lactol with a Wittig reagent or a Wittig-Horner reagent in the presence of a basic substance (n, R, Rand Rare as defined in the description). 【課題】アシルオキシ基を有するアルケン化合物を簡単で工程数が少なく、より安価に製造できる方法を提供する。【解決手段】アシル化されたラクトールを、塩基性物質の存在下でウィッティヒ試薬、またはウィッティヒ−ホーナー試薬と反応させる工程を含む、下記一般式（１）で表される化合物の製造方法（ｎ、Ｒ1、Ｒ2およびＲ3は明細書で定義される）に関する。式（１）【選択図】なし
Bibliography:Application Number: JP20130173317