PRODUCTION OF ALKYLHALOSILANE

PROBLEM TO BE SOLVED: To obtain an alkylhalosilane useful in an organic silane industry in improved selectivity and in a high yield by reacting an alkyl halide with a catalyst aggregate containing powder silicon and a copper catalyst in the presence of an organic phosphine at a specific temperature....

Full description

Saved in:
Bibliographic Details
Main Authors BABLIN JOHN MATTHEW, LEWIS LARRY NEIL
Format Patent
LanguageEnglish
Published 06.06.2000
Edition7
Subjects
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
Online AccessGet full text

Cover

More Information
Summary:PROBLEM TO BE SOLVED: To obtain an alkylhalosilane useful in an organic silane industry in improved selectivity and in a high yield by reacting an alkyl halide with a catalyst aggregate containing powder silicon and a copper catalyst in the presence of an organic phosphine at a specific temperature. SOLUTION: This method for producing an alkylhalosilane (for example, dimethyldichlorosilane) comprises directly reacting (A) an alkyl halide (for example, methyl chloride) with (B) a catalyst aggregate containing powder silicon and a copper catalyst at a temperature of about 250-350 deg.C. Therein, an organic phosphine such as trimethylphosphine, triethylphosphine or triphenylphosphine is used for the reaction in an amount effective for the direct reaction. Thereby, the objective alkylhalosilane such as a dimethyldihalosilane important in an organic silane industry is produced in high productivity and in improved selectivity.
Bibliography:Application Number: JP19990271495