PROCEDE DE PRODUCTION DE TRIOXYDE D'ANTIMOINE AYANT UNE FAIBLE INTENSITE D'EMISSION DE RAYONS ALPHA

• Main Author: HIROSHI NAKAHIRA ET SHIGEKI KUBO
• Format: Patent
• Language: French
• Published: 30.11.1984
• Subjects: BASIC ELECTRIC ELEMENTS; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR; ELECTRICITY; INORGANIC CHEMISTRY; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; SEMICONDUCTOR DEVICES; THEIR PREPARATION OR CHEMICAL WORKING-UP; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS

L'INVENTION SE RAPPORTE A LA PRODUCTION DE TRIOXYDE D'ANTIMOINE AYANT UNE INTENSITE D'EMISSION DE RAYONS ALPHA REDUITE.SELON LE PROCEDE DE L'INVENTION, ON AJOUTE AU MOINS UNE QUANTITE EQUIVALENTE D'ACIDE CHLORHYDRIQUE CONCENTRE A DU TRIOXYDE D'ANTIMOINE CONTENANT UNE SUBSTANCE QUI EMET DES RAYONS ALPHA, ON LES MELANGE PAR AGITATION ET ON SEPARE TOUT RESIDU NON DISSOUS DE FACON A OBTENIR UNE SOLUTION AQUEUSE DE CHLORURE D'ANTIMOINE; ON AJOUTE A CETTE SOLUTION UN VOLUME AU MOINS DECUPLE D'EAU ET ON AGITE A UNE TEMPERATURE D'AU MOINS 60C DE FACON A CAUSER LA PRECIPITATION DU TRIOXYDE D'ANTIMOINE; ON SEPARE PAR FILTRATION LE TRIOXYDE D'ANTIMOINE PRECIPITE; ET ON LAVE LE TRIOXYDE D'ANTIMOINE PRECIPITE AVEC AU MOINS 10 FOIS SON POIDS D'EAU CHAUDE AYANT UNE TEMPERATURE DE 60C, ET ON SECHE.LE PRODUIT RESULTANT EST UTILE DANS LA FABRICATION DE CIRCUITS INTEGRES. At least an equivalent amount of concentrated hydrochloric acid is added to antimony trioxide containing a substance emitting alpha rays, and they are stirred. Any undissolved residue is removed to prepare an aqueous solution of antimony chloride. Water is added to the solution, or a distillate obtained by distilling it at a temperature of at least 135 DEG C. The quantity of the water is at least 10 times by volume as much as the solution, or at least 20 times by volume as much as the distillate. The solution or distillate and the water are stirred at a temperature of at least 60 DEG C. to cause precipitation of antimony trioxide, and the precipitate is separated by filtration. The precipitate is washed with at least 10 times by weight as much warm water having a temperature of 60 DEG C., and dried. This antimony trioxide has an alpha-ray strength not exceeding 0.01 C/cm2 per hour, does not contain more than 1 ppm of any impurities such as arsenic, lead or soluble chlorine, and has a large average particle size.