Menetelmä stereosäännöllisten polymeerien valmistamiseksi, joilla on ahtaissa rajoissa oleva molekyylipainojakautuma

Stereoregular polymers having a molecular weight distribution of less than 5.0 and an isotactic index in excess of 96 percent are produced by polymerizing an alpha-olefin having 3 to 8 carbon atoms in a low pressure gas phase fluid bed process at a temperature in excess of 80 DEG C employing a heat...

Full description

Saved in:
Bibliographic Details
Main Authors BRADY,III, ROBERT CONVERSE, LIU,HAN TAI, NOSHAY,ALLEN, STAKEM,FRANCIS GREGORY
Format Patent
LanguageFinnish
Swedish
Published 10.01.1995
Edition5
Subjects
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
Online AccessGet full text

Cover

More Information
Summary:Stereoregular polymers having a molecular weight distribution of less than 5.0 and an isotactic index in excess of 96 percent are produced by polymerizing an alpha-olefin having 3 to 8 carbon atoms in a low pressure gas phase fluid bed process at a temperature in excess of 80 DEG C employing a heat stable catalyst system comprising (a) a solid catalyst component containing magnesium, titanium, halide and a polycarboxylic acid ester containing two coplanar ester groups attached to adjacent carbon atoms, as inside electron donor, (b) an organoaluminum cocatalyst, and (c) a silicon compound containing a silicon-oxygen-carbon linkage, as outside electron donor.
Bibliography:Application Number: FI19880002323