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Summary:To provide a piston ring comprising a hard carbon film that is easy to form and exhibits excellent wear resistance. The above-described problem is solved by having a hard carbon film 4 formed on at least an outer peripheral sliding surface 11 of a piston ring base material 1, wherein the hard carbon film 4 is a laminated film comprising a plurality of layers, and is configured so as to contain boron within a range of an atomic density of 0.2 x 10 22 atoms/cm 3 to 2.0 x 10 22 atoms/cm 3 inclusive. This hard carbon film 4 may be configured to have an sp 2 component ratio within a range of 40% to 80% inclusive, measured in a TEM-EELS spectrum formed by combining electron energy loss spectroscopy (EELS) with a transmission electron microscope (TEM), and a hydrogen content within a range of 0.1 atom% to 5 atom% inclusive. Further, a total thickness of this hard carbon film 4 may be configured to be within a range of 0.5 µm to 20 µm inclusive.
Bibliography:Application Number: EP20160832938