POLYMER, COMPOSITION AND USE

• Main Authors: SWAANS, Roel Johannes Marinus, KOK, DE, Paul, TENNEBROEK, Ronald
• Format: Patent
• Language: English; French; German
• Published: 27.05.2020
• Subjects: ADHESIVES; CHEMICAL PAINT OR INK REMOVERS; CHEMISTRY; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS; COMPOSITIONS BASED THEREON; CORRECTING FLUIDS; DYES; FILLING PASTES; INKS; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; POLISHES; THEIR PREPARATION OR CHEMICAL WORKING-UP; USE OF MATERIALS THEREFOR; WOODSTAINS

There is described a process for preparing a Schiff base crosslinkable aqueous dispersion of a polyurethane A (PUD) the process comprising (a) reacting components (1) to (4) as present to form an acidic isocyanate terminated prepolymer that comprises anionic or potentially anionic functional groups thereon; where: (1) component one comprises 10 to 80% by weight of at least one polyisocyanate optionally containing at least one anionic or potentially anionic dispersing group; (2) optional component two comprises up to 15% by weight of at least one isocyanate-reactive polyol containing at least one anionic or potentially anionic dispersing group; (3) component three comprises 15 to 85% by weight of at least one isocyanate reactive polyol other than component two if present, and having a weight average molecular weight greater than or equal to 500 Daltons optionally containing at least one anionic or potentially anionic dispersing group; and (4) optional component four comprises up to 20% by weight of at least one isocyanate reactive polyol other than component three and two if present and having a weight average molecular weight less than 500 Daltons; where if component two is not present component one or three contains at least one anionic or potentially anionic dispersing group; where the amounts of components one to four are expressed as a weight percentage calculated from the total amount of the above components (i.e. one and three and optional two and/or four where present) being 100%; and where the mixture used in step (a) is substantially free of volatile amines and N-alkyl pyrrolidinones; (b) adding to the reaction mixture from step (a) an alkali metal neutralising agent in an amount from 0.05 to 6 parts by weight substantially to neutralise the isocyanate terminated prepolymer obtained from step (a); where the amount (in weight parts) of the alkali metal neutralising agent is calculated based on the weight of alkali metal in the neutralising agent relative to the total amount of components one to four in step (a) being equal to 100 parts; and (c) reacting the neutralised prepolymer from step (b) with an active hydrogen compound to extend the chain of the prepolymer to form an aqueous dispersion of polyurethane A. and (ii) 90 to 5% by weight of a vinyl polymer B wherein the weight % amounts of (i) and (ii) are calculated as a percentage of the total amount of (i) and (ii) and these percentages add up to 100%; and where the composition is: substantially free of volatile amines and N-alkyl pyrrolidinones (preferably solvent free); and is neutralised with a metal neutralising agent and the composition comprises a polyamine of polyhydrazide compound. Another aspect of the invention provides an aqueous coating obtained from the above process, in which polyurethane A and/or vinyl polymer B is Schiff base cross-linkable under ambient conditions.