METHOD FOR THE MANUFACTURE OF A POLYHYDROXY-CARBOXYLIC ACID

• Main Authors: KUSZLIK, ANDRZEJ, STEPANSKI, MANFRED, LOVIAT, FRANCOIS
• Format: Patent
• Language: English; French; German
• Published: 25.12.2013
• Subjects: CHEMISTRY; COMPOSITIONS BASED THEREON; HETEROCYCLIC COMPOUNDS; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; SEPARATION; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING

Disclosed is a method to prepare a polylactic acid comprising the steps of performing a ring opening polymerization using a catalyst and either a catalyst killer compound or an endcapping additive to obtain a raw polylactic acid of MW greater than 10,000 g/mol, purifying the raw polylactic acid by removing and separating low boiling compounds comprising lactide and impurities from the raw polylactic acid by devolatization of the low boiling compounds as a gas phase stream, and purifying the lactide from the devolatization and removing the impurities from the gas phase stream of evaporated low boiling compounds by means of crystallization by desublimation from the gas phase, wherein the lactide is purified and the removed impurities include a catalyst residue and a compound containing at least one hydroxyl group such that the purified lactide is then polymerized by feeding it back into the ring opening polymerization. The invention further relates to an apparatus for carrying out the method comprising a polymerization reactor for performing a ring opening polymerization to obtain a raw polylactic acid, a devolatization apparatus for separating low boiling compounds comprising lactide and impurities from a raw polylactic acid, and a crystallization apparatus for purifying a lactide and removing impurities by means of a desublimation and a crystallization in the same crystallization apparatus.