VINYL ESTER/ETHYLENE-BASED BINDERS FOR PAPER AND PAPERBOARD COATINGS

• Main Authors: CONFALONE, PHILIP, FARWAHA, RAJEEV, GOHR, KERSTIN
• Format: Patent
• Language: English; French; German
• Published: 14.05.2014
• Subjects: ADHESIVES; CHEMICAL PAINT OR INK REMOVERS; CHEMISTRY; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS; COMPOSITIONS BASED THEREON; CORRECTING FLUIDS; DYES; FILLING PASTES; IMPREGNATING OR COATING OF PAPER; INKS; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; PAPER NOT OTHERWISE PROVIDED FOR; PAPER-MAKING; PASTES OR SOLIDS FOR COLOURING OR PRINTING; POLISHES; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; PRODUCTION OF CELLULOSE; PULP COMPOSITIONS; TEXTILES; THEIR PREPARATION OR CHEMICAL WORKING-UP; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; USE OF MATERIALS THEREFOR; WOODSTAINS

Disclosed are surfactant-stabilized latex emulsions which can be used as binders in paper coating compositions. Such latex emulsions comprise an interpolymer formed by emulsion polymerizing monomers selected from vinyl esters, e.g., vineyl acetate; ethylene; certain unsaturated mono- and di-carboxylic acid materials such as acrylic acid or maleic anhydride; and certain polyethylenically unsaturated cross-linking co-monomers such as diallyl phthalate. These latex emulsions are stabilized with surfactants which are substantially free of environmentally suspect alkyl phenol ethoxylates (APEs). The paper coating compositions containing latex emulsion binders of this type exhibit especially desirable coating strength as quantified by the Dry Pick Values (as defined herein) which such compositions provide.