REACTION WITH PRIMARY ALLYLIC ALCOHOLS

The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2',6,6'-tetra-methylpiperidin-1-oxyl) or its derivates an...

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Bibliographic Details
Main Authors HINZE, RAMONA, EGGERSDORFER, MANFRED, L, BONRATH, WERNER, VALKENBERG, MICHAEL, H, ECKHARDT, JEAN-FRANCOIS, HOELDERICH, WOLFGANG, F
Format Patent
LanguageEnglish
French
German
Published 11.11.2009
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Summary:The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2',6,6'-tetra-methylpiperidin-1-oxyl) or its derivates and c) a co-oxidants selected from the group of peroxodisulfates (PDS), H2SO5, H2O2, NaOCl, O2, KOCl, and air.
Bibliography:Application Number: EP20080715790