A PROCESS FOR THE PREPARATION OF POLYETHYLENE
A process for preparing high density polyethylene in the gas phase comprising contacting a mixture comprising ethylene and one or more alpha-olefins with the supported reaction product of a bis-hydrocarbylsilyl chromate and a hydrocarbylaluminum compound or a hydrocarbyl boron compound in a fluidize...
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Main Authors | , , , |
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Format | Patent |
Language | English French German |
Published |
31.05.2000
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Edition | 7 |
Subjects | |
Online Access | Get full text |
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Summary: | A process for preparing high density polyethylene in the gas phase comprising contacting a mixture comprising ethylene and one or more alpha-olefins with the supported reaction product of a bis-hydrocarbylsilyl chromate and a hydrocarbylaluminum compound or a hydrocarbyl boron compound in a fluidized bed reactor having a recycle gas line, under particularly defined polymerization conditions, including, but not limited to, the following provisos: (i) oxygen and/or another catalyst poison is introduced into the reactor in the range of about 0.005 to about 0.5 part by volume of catalyst poison per million parts by volume of ethylene; and (ii) a relatively low boiling inert hydrocarbon is introduced into the recycle gas line in an amount sufficient to raise the dew point of the recycle gas, which is comprised of alpha-olefins and other reactor gases, and the recycle gas is partially condensed and recycled to the reactor where it promotes cooling by evaporation. |
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Bibliography: | Application Number: EP19980940884 |