(Meth)acrylic acid polymer and manufacturing method thereof

A (meth)acrylic acid polymer is obtained by conducting a polymerization reaction using 60 mol% or more of a hydrophilic monomer containing (meth)acrylic acid and a combination of at least one kind of persulfate salts and at least one kind of bisulfite salts as an initiator series under conditions th...

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Bibliographic Details
Main Authors MAEDA, YOSHIHIRO, YAMAGUCHI, SHIGERU, ISHIDA, TAMAO
Format Patent
LanguageEnglish
French
German
Published 12.05.2004
Edition7
Subjects
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Summary:A (meth)acrylic acid polymer is obtained by conducting a polymerization reaction using 60 mol% or more of a hydrophilic monomer containing (meth)acrylic acid and a combination of at least one kind of persulfate salts and at least one kind of bisulfite salts as an initiator series under conditions that a pH is smaller than 5 and a degree of neutralization is smaller than 40 mol%, in such a manner that a solid concentration when the polymerization reaction ends is 40% or higher. The resulting polymer has a weight average molecular weight ranging from 3,000 to 15,000, a sulfonic acid group at an end terminal, and an anti-gelling ability Q-value smaller than 2.0, where the anti-gelling ability Q-value is defined as: Consequently, it has become possible to provide a low-molecular-weight (meth)acrylic acid polymer having not only excellent dispersing ability and chleating ability, but also high resistance to gelling, and an efficient manufacturing method of such a polymer.
Bibliography:Application Number: EP19990301647