Process for manufacturing 4,4'-methylene-bis-(dibutyl-dithiocarbamate)

• Main Authors: FORSTNER, JANOS, PETRO, JOZSEF, SZABOLCS, SZOBOSZLAY, RAKSI, GYULA, SZTREHARSZKI, GYULA, BALDADINCZ, JENO, CSERGO, KAROLY, FEKETE, IMRE, KISS, JANOS, JOVER, BELA, MIKO, FERENC, TOTH, JOZSEF
• Format: Patent
• Language: English; French; German
• Published: 09.06.1999
• Edition: 6
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; CHEMISTRY; FUELS; LUBRICANTS; LUBRICATING COMPOSITIONS; METALLURGY; ORGANIC CHEMISTRY; PEAT; PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION

The subject-matter of the invention is a process for manufacturing 4,4'-methylene-bis-(dibutyl-dithiocarbamate) with ASTM colour less than 2, by reacting aqueous solutions of dibutyl amine and sodium hydroxide with carbon disulfide at a temperature below 42 DEG C, treating the obtained reaction product with methylene dichloride followed by vacuum stripping at a temperature below 122 DEG C and a pressure above 5 kPa, phase separation and filtration of the precipitated sodium chloride, characterized by keeping the temperature of the mixture during the reaction with carbon disulfide at or below 15 DEG C and performing the vacuum stripping in 2 steps, first at a temperature of from 45 DEG C to 100 DEG C and at a pressure of from 5 to 50 kPa, then carrying out the phase separation at 35 DEG C to 50 DEG C, and thereafter performing the second vacuum stripping of the separated organic phase also at a temperature of from 45 DEG C to 100 DEG C and at a pressure of from 5 to 50 kPa.