Thermal dye bleach construction

• Main Authors: HELLAND, RANDALL H, TIERS, GEORGE V. D, STEVENSON, DIAN E
• Format: Patent
• Language: English; French; German
• Published: 01.12.1993
• Edition: 5
• Subjects: AUXILIARY PROCESSES IN PHOTOGRAPHY; CINEMATOGRAPHY; COLOUR PRINTING; ELECTROGRAPHY; HOLOGRAPHY; LINING MACHINES; PERFORMING OPERATIONS; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES; PHOTOGRAPHY; PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHYSICS; PRINTING; PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; STAMPS; TRANSPORTING; TYPEWRITERS

A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a styryl dye having a nucleus of general formula (I): representing the nucleus of a styryl dye in which R = methyl or ethyl group Y = alkoxy of 1 to 20 carbon atoms m = 1 or 2, n = 1, 2, or 3, and x<(-)> = an anion The aromatic fused benzene portion of the indolenine ring may be further substituted with commonly acceptable dye substituents such as alkyl and substituted alkyl (of 1 to 10 carbon atoms) groups, alkoxy groups (preferably of 1 to 10 carbon atoms), fused aromatic rings (as to make the benzene ring a fused naphthalene ring), halogen (including fluoro), cyano, nitro, carboxamido, amido, etc. One or two substituents chosen variously from said group may also be present on the phenyl ring to which the alkoxy group is attached. These substituents and their combinations should not be chosen so as to alter the absorption characteristics of the dye greatly enough to remove the maximum absorption from between 300 and 490 nm. X<(-)> may be any anion, but certain classes of anions and certain particular anions are preferred. Aromatic and perfluorinated anions and, in particular dodecylbenzenesulfonate and especially perfluoro(ethylcyclohexane sulfonate) are preferred on account of their solubilizing power, but simpler anions such as iodide, chloride, bromide, methylsulfate, perchlorate and the like may also be used.