VERFAHREN ZUR POLOLEFINHERSTELLUNG UND GASPHASENPOLYMERISATIONSAPPARAT

• Main Authors: TODA, MASATOSHI, NAMBU, TOMOO, AIDA, MASAO
• Format: Patent
• Language: German
• Published: 16.06.2005
• Edition: 7
• Subjects: CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP

Provided is a continuous vapor-phase polymerization method for producing polyolefins. In the method, polymer agglomerates and aggregates are prevented from being formed, and polymer deposition on the wall of reactors and around stirring blades is prevented. The method enables continuous and stable production of high-quality polyolefins, with no pipe line clogging. The method is characterized by a specific supply mode of feeding a catalyst activity retardant such as alcohol into polymerization reactors. Specifically, the retardant is fed into the vapor phase in a polymerization reactor and into the powder phase therein through its side wall. Preferably, the retardant is fed into the powder phase through a plurality of sites of the side wall of the reactor.