Polar reactive fullerene-azirine derivs. useful in opto-electrical devices

Fullerene-azirine derivs. of formula (I) and fullerene-oxazole and thiazole derivs. of formula (IV) are new: F = a fullerene radical of formula C20+2m (m = 2-100); X = C(O), SO2, S(O), P(O)R, P(S)R or PR; R = 1-20 C alkyl, 6-14 C aryl-(1-10 C) alkyl or 6-14 C aryl, in which the alkyl gps. may have 1...

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Main Authors MATTAY, JOCHEN, DR., 48341 ALTENBERGE, DE, JACOBI, DIRK., 13189 BERLIN, DE, AVERDUNG, JOHANNES., 48149 MUENSTER, DE, BINGEL, CARSTEN., 65830 KRIFTEL, DE, ABRAHAM, WERNER, DR., 16547 BIRKENWERDER, DE
Format Patent
LanguageEnglish
German
Published 08.02.1996
Edition6
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Summary:Fullerene-azirine derivs. of formula (I) and fullerene-oxazole and thiazole derivs. of formula (IV) are new: F = a fullerene radical of formula C20+2m (m = 2-100); X = C(O), SO2, S(O), P(O)R, P(S)R or PR; R = 1-20 C alkyl, 6-14 C aryl-(1-10 C) alkyl or 6-14 C aryl, in which the alkyl gps. may have 1 or more non-adjacent CH2 gps. replaced by -C=C-, -CH=CH-, -O-, -S-, -COO-, -SiR2- and/or -C(O)-, the alkyl and aryl gps. may have 1 or more OH, OR1, COOR, OCOR, F, Cl, Br, NO2, CN, NHCOR1 or NR1COR1 substits. and the aryl gps. may also be substd. by R1 (R1 = 1-6 C alkyl); n = 1-10+m; Z1 = C, S, S(O) or P; and Z2 = O or S.
Bibliography:Application Number: DE19944427489