VERFAHREN ZUR HERSTELLUNG VON DIALDEHYDEN

A process for preparing a dialdehyde which comprises subjecting a glycol to oxidation-dehydrogenation in the presence of silver particles of which the surface is partially coated with a silicon carbide powder or a silicon nitride powder. According to the present invention, dialdehydes can be prepare...

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Bibliographic Details
Main Authors UNO, YOSHINOBU, GIFU, JP, KOHDA, HIROMICHI, HIRAKATA, JP, TOIYAMA, MASAOKI, NAKAGAWA, SUMIO, OGAKI, GIFU, JP
Format Patent
LanguageGerman
Published 31.08.1989
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Summary:A process for preparing a dialdehyde which comprises subjecting a glycol to oxidation-dehydrogenation in the presence of silver particles of which the surface is partially coated with a silicon carbide powder or a silicon nitride powder. According to the present invention, dialdehydes can be prepared from glycols in high conversion of the glycol in high selectivity into the dialdehyde, and the silver catalyst can be reused even if the reaction is stopped in a while since the silver particles are not aggregated during long time operation.
Bibliography:Application Number: DE19893904829