New reactive dyestuff cpds. for dyeing e.g. cotton, wool - with vinyl or substd. ethyl sulphonyl benzyl or phenyl-ethyl amino heterocyclyl substit

New vinyl- or beta-substd.-ethyl-sulphonylbenzyl- or phenethyl-amino-N-heterocyclyl dyestuff cpds are of the formula F - (A - Q)n (I); (where Q = a gp of formula (II): F = a dyestuff radical; m and n = 1 or 2; A = a linking gp or direct bond; W = a reactive gp of the halo-N-heterocyclic series; R1 =...

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Bibliographic Details
Main Author IDEN, RUEDIGER., 6720 SPEYER, DE
Format Patent
LanguageEnglish
German
Published 25.02.1988
Edition4
Subjects
ADHESIVES
CHEMISTRY
DYES
LAKES
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
MORDANTS
NATURAL RESINS
ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES
PAINTS
POLISHES
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Summary:New vinyl- or beta-substd.-ethyl-sulphonylbenzyl- or phenethyl-amino-N-heterocyclyl dyestuff cpds are of the formula F - (A - Q)n (I); (where Q = a gp of formula (II): F = a dyestuff radical; m and n = 1 or 2; A = a linking gp or direct bond; W = a reactive gp of the halo-N-heterocyclic series; R1 = H or 1-4C alkyl; R2 = H or Me; X = H, O-alkyl, O-aryl, NH-alkyl, NH-aryl, halogen, NO2, -SO2-alkyl, -SO2-aryl, -COOH, -CONH-alkyl, -CONH-aryl, -COO-alkyl or -COO-aryl; Y = H, halogen or 1-4C alkyl; Z = -CH=CH2 or -CH2-CH2-Z1; Z1 = OSO3H, SSO3H, OPO3H2, OCOCH3, OCOH or carboxypyridinium: Cpds with m = 1, -SO2-Z in the para-position to the -CHIR2)- gp. and X and/or Y = H, 1-4C alkyl, halogen or 1-4C alkoxy are excluded.). USE/ADVANTAGE - (I) are claimed for dyeing fibrous material contg. OH and carbonamido gps. The Q gp gives optimum substantivity. (I) are useful for dyeing wool and esp cotton, pref. by the exhaustion method at 40-90 deg C and the cold dwell process. Applicn in a wide temp range is possible and (I) give high yields and a high deg of fixing.
Bibliography:Application Number: DE19863628090