VERFAHREN ZUR HERSTELLUNG VON POLYMERISATEN DER VINYLPHOSPHONSAEURE IN PROTISCHEN LOESUNGSMITTELN

• Main Authors: ENGELHARDT,FRIEDRICH,DR, DUERSCH,WALTER,DR, HERWIG,WALTER,DR
• Format: Patent
• Language: German
• Published: 05.07.1984
• Subjects: ADHESIVES; CHEMICAL PAINT OR INK REMOVERS; CHEMICAL SURFACE TREATMENT; CHEMISTRY; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS; COATING MATERIAL WITH METALLIC MATERIAL; COATING METALLIC MATERIAL; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; CORRECTING FLUIDS; DIFFUSION TREATMENT OF METALLIC MATERIAL; DYES; FILLING PASTES; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL; INKS; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLICMATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASSC23 AND AT LEAST ONEPROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25; NATURAL RESINS; NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; POLISHES; THEIR PREPARATION OR CHEMICAL WORKING-UP; USE OF MATERIALS THEREFOR; WOODSTAINS

Process for the preparation of polymers of vinylphosphonic acid in protic diluents with the aid of catalysts which form free radicals, which comprises heating vinylphosphonic acid at temperatures of 40 DEG to 130 DEG C. in a total of 10 to 150% by weight of protic diluents for a total of 4-60 hours in the presence of 1.0 to 5.5% by weight of aliphatic peroxy-esters, diacyl peroxides and/or aliphatic azo compounds which decompose by half in one hour at temperatures below 122 DEG C.