Verfahren zur Herstellung von aromatischen Aethern

• Main Authors: HANS SPIEGELBERG,DR, HENRI RAMUZ,DR, ALBRECHT EDENHOFER,DR
• Format: Patent
• Language: German
• Published: 17.12.1970
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; CHEMISTRY; HETEROCYCLIC COMPOUNDS; HUMAN NECESSITIES; HYGIENE; MEDICAL OR VETERINARY SCIENCE; METALLURGY; ORGANIC CHEMISTRY; PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

Oxazolidones-(2) substituted in the 5-position are prepared by reaction of triglycidyl isocyanurate of the general formula <FORM:1085106/C2/1> at elevated temperatures with organic nitrogen containing compounds which contain a hydrogen atom capable of reacting with epoxide compounds attached to the nitrogen atom, for example secondary amines, heterocyclic nitrogen compounds, open chain or cyclic sulphonic or carboxylic acid amides, open chain or cyclic imides, which may also contain substituents which are insert to or react only slowly with epoxides. Novel products include 5-[(N-methyl-N-phenyl) - aminomethyl] - oxazolidone - (2), N (p nitrophenyl) - N - [(oxazolidone - (2) - yl - (5)) - methyl] - acetamide, 5 - (phthalimidomethyl) - oxazolidone - (2), N - methyl - N - [(oxazolidone - (2) - yl - (5)) - methyl] - p - toluenesulphonamide, N - [(oxazolidone - (2)-yl - (5)) - methyl] - saccharin, 5 - piperidinomethyl - oxazolidone - (2) and 5 - morpholinomethyl-oxazolidone-(2). Tris - (2 - hydroxy - 3 - N - morpholinopropyl) isocyanurate is isolated as an intermediate in the above reaction.