Verfahren zur Herstellung der metallorganischen Komponente eines zur Polymerisation von ª‡-Olefinen geeigneten, Aluminium- und Berylliumverbindungen enthaltenden Mischkatalysators

• Main Authors: D'ALESSANDRO VINCENZO, MORETTI GIORGIO, DINI FRANCESCO
• Format: Patent
• Language: German
• Published: 20.02.1964
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP

An organometallic component for a catalytic system for the polymerization of olefines comprises a dialkylberyllium compound, an organoaluminium compound an an ether in an amount chemically equivalent to the organoaluminium compound, i.e. 1 mol. of ether per mol. of organoaluminium compound. The organometallic component may be made by alkylating a beryllium salt with an organoaluminium compound either in the presence of, or with the subsequent addition of, an ether. This process may be a one-step process, for example triethylaluminium and beryllium dichloride may be reacted together, there being a 150% excess of the triethylaluminium <FORM:0921806/IV(a)/1> The diethylberyllium need not be separated, it being only necessary to add, at the end of the reaction, the chemically equivalent amount of ether with respect t the alkylaluminium compounds present. In a two-step process, beryllium dichloride and triethylaluminium are reacted at a molar ratio of 1:1, <FORM:0921806/IV(a)/2> the diethylaluminium monochloride is distilled off and the residual beryllium salt is further alkylated with triethyl aluminium <FORM:0921806/IV(a)/3> In practice an excess of aluminium triethyl must be used. All these reactions are preferably carried out in a concentrated medium and at a temperature of 20 DEG to 120 DEG C. The alkylations may be carried out in the presence of solvents which are inert under the reaction conditions. Alternatively in the two-step process the ethylberyllium monochloride obtained is dehalogenated with an alkali metal hydride, <FORM:0921806/IV(a)/4> and the ethylberyllium hydride obtained is reacted with an olefine, e.g. C2H4, under a pressure of 1 to 20 atoms. and at reaction temperatures between 20 DEG and 100 DEG C. to give diethylberyllium. The reaction is carried out in a solvent, e.g. ether or a dispersant, e.g. a saturated or an aromatic hydrocarbon. A molecular complex of sodium hydride and triethyl aluminium may be used in place of sodium hydride. Olefines may be polymerized using the organo-metallic component of the invention together with a transition metal halide. Propylene and butene-1 are mentioned. Specification 882,560 is referred to.