Process for producing n-(1-(2,4-dichlorophenyl)ethyl)-2- cyano-3,3-dimethylbutanamide

• Main Author: KATUHISA MASUMOTO,ETSUKO HARADA,HIDEYUKI GOTO,KOJI HAGIYA,KIYOTO MAEDA,MAKOTO FUJIMURA,MASASHI SAHARA,OSAMU MAGARA,YOSHIMI YAMADA
• Format: Patent
• Language: Chinese; English
• Published: 01.09.2004
• Edition: 7
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; AGRICULTURE; ANIMAL HUSBANDRY; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; CHEMISTRY; FISHING; FORESTRY; HUMAN NECESSITIES; HUNTING; METALLURGY; ORGANIC CHEMISTRY; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF; TRAPPING

N-[1-(2，4-二氯苯基)乙基]-2-氰基-3，3-二甲基丁烷酰胺的制造方法，其特征是，使α-氰基-叔丁乙酸的C#-[2]-C#-[4]烷基酯和1-(2，4-二氯苯基)乙胺在130～250℃下反应。 PURPOSE: Provided are an optically active or racemPURPOSE: Provided are an optically active or racemic intermediate compound for producing N-£1-(2,4-dic intermediate compound for producing N-£1-(2,4-dichlorophenyl)ethyl|-2-cyano-3,3-dimethylbutaneamiichlorophenyl)ethyl|-2-cyano-3,3-dimethylbutaneamide useful as a plant vermin exterminating agent, ade useful as a plant vermin exterminating agent, and a method for preparing the same. CONSTITUTION: nd a method for preparing the same. CONSTITUTION: The intermediate compound is optically active N-(aThe intermediate compound is optically active N-(alpha-methyl-2,4- dichlorobenzylidene)-alpha-(2,4-dlpha-methyl-2,4- dichlorobenzylidene)-alpha-(2,4-dichlorophenyl)ethylamine, which is obtained from tichlorophenyl)ethylamine, which is obtained from the condensation of optically active 1-(2,4-dichlorhe condensation of optically active 1-(2,4-dichlorophenyl)ethylamine with 2,4-dichloro acetophenone.ophenyl)ethylamine with 2,4-dichloro acetophenone. Alternatively, racemic N-(alpha-methyl-2,4-dichlo Alternatively, racemic N-(alpha-methyl-2,4-dichlorobenzylidene)-alpha- (2,4-dichlorophenyl)ethylamirobenzylidene)-alpha- (2,4-dichlorophenyl)ethylamine is obtained by subjecting optically active N-(ane is obtained by subjecting optically active N-(alpha- methyl-2,4-dichlorobenzylidene)-alpha-(2,4-dlpha- methyl-2,4-dichlorobenzylidene)-alpha-(2,4-dichlorophenyl)ethylamine to the action of an alkalichlorophenyl)ethylamine to the action of an alkali metal alkoxide in the presence of dimethyl sulfoi metal alkoxide in the presence of dimethyl sulfoxide. xide.