Tetranuclear organic-metal macrocyclic compound as well as preparation method and application thereof

• Main Authors: DANG LILONG, ZHANG TINGTING, CHANG XINHONG, MA LUFANG, CHEN TIAN
• Format: Patent
• Language: Chinese; English
• Published: 15.08.2023
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; HUMAN NECESSITIES; HYGIENE; MEDICAL OR VETERINARY SCIENCE; METALLURGY; ORGANIC CHEMISTRY; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES; SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS ORMEDICINAL PREPARATIONS; THEIR RELEVANT APPARATUS; TRANSPORTING

The invention belongs to the technical field of organic synthesis, and particularly relates to a tetranuclear organic-metal macrocyclic compound as well as a preparation method and application thereof. The invention provides a tetranuclear organic-metal macrocyclic compound which has a structure as shown in a formula I. The tetranuclear organic-metal macrocyclic compound contains four rhodium, and the four rhodium are connected to form a rectangle. The width of the rectangle is equal to the length of the rectangle, the center distance between a benzene ring 1 and a benzene ring 2 in the tetranuclear organic-metal macrocyclic compound is equal to the center distance between a benzene ring 3 and a benzene ring 4 in the tetranuclear organic-metal macrocyclic compound. The material has an obvious pi-pi accumulation effect, and has a potential application prospect in the fields of catalysis and photo-thermal conversion. 本发明属于有机合成技术领域，具体涉及一种四核有机-金属大环化合物及其制备方法和应用。本发明提供了一种四核有机-金属大环化合物，所述四核有机-金属大环化合物具有如式Ⅰ所示结构，所述四核有机-金