Ionic carbamyl iron carbonyl compound as well as preparation method and application thereof

• Main Authors: CUI CHUANGUO, LIU XIAOMING, GUO JINZHONG, GUO ZHUMING, XIAO ZHIYIN
• Format: Patent
• Language: Chinese; English
• Published: 01.03.2022
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; BASIC ELECTRIC ELEMENTS; CHEMISTRY; ELECTRICITY; HUMAN NECESSITIES; HYGIENE; INDUCTANCES; MAGNETS; MEDICAL OR VETERINARY SCIENCE; METALLURGY; ORGANIC CHEMISTRY; PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES; TRANSFORMERS

The invention discloses an ionic carbamyl iron carbonyl compound which has a structure as shown in a formula (1). The invention discloses a preparation method of the compound, and the preparation method comprises the following specific steps: under certain solvent and reaction conditions, reacting [Fe (CO) 4Br2] with a proper amount of organic amine for a certain time, and separating and purifying to obtain a target compound. The invention also discloses an application of the compound in the aspect of carbon monoxide sustained-release medicines and an application of the compound as a precursor in preparation of a ferromagnetic material. 本发明公开了一类离子型胺甲酰铁羰基化合物，具有如式(1)所示的结构：本发明公开了这类化合物的制备方法，具体步骤包括：在一定溶剂和反应条件下，由[Fe(CO)4Br2]与合适量的有机胺反应一定时间，经分离纯化既得到目标化合物。本发明还公开了这类化合物在缓释一氧化碳药物方面的应用，以及作为前驱物制备铁磁性材料中的应用。