Polymerizable compounds

Polymerizable compounds based on N-acylamido-piperazines are provided. Such compounds have the formula: wherein: R1, R2, and R3 are each independently selected from the group consisting of hydrogen and lower alkyl, B is a linking group selected from the group consisting of carbonyl, sulfonyl, amide,...

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Bibliographic Details
Main Author PAUL E. SHARE
Format Patent
LanguageEnglish
Published 10.07.1996
Edition6
Subjects
ADHESIVES
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
COMPOSITIONS BASED THEREON
CORRECTING FLUIDS
DYES
FILLING PASTES
HETEROCYCLIC COMPOUNDS
INKS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF MATERIALS THEREFOR
WOODSTAINS
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Summary:Polymerizable compounds based on N-acylamido-piperazines are provided. Such compounds have the formula: wherein: R1, R2, and R3 are each independently selected from the group consisting of hydrogen and lower alkyl, B is a linking group selected from the group consisting of carbonyl, sulfonyl, amide, and carboxyl; n is one or zero; R4 is a radical selected from the group consisting of a higher aliphatic group (i.e. at least four carbon atoms, preferably from about 6 to about 50 carbon atoms), a substituted higher aliphatic group, an alicyclic group, a heterocyclic group a non-benzenoid aromatic group, and a substituted aromatic group. These compounds can be incorporated into a polymerizable composition. The compounds is preferably present in said composition in a major amount on a mole percent basis of th polymerizable monomers. These polymerizable compositions are useful as coatings, particularly in formulations containing a photoinitiator susceptible to ultra-violet radiation. The coating is exposed to ultra-violet radiation sufficient to cause the compound to polymerize and thus cure the coating.
Bibliography:Application Number: CN19941092633