Cluster phthalocyanine binary molecule photosensitizer as well as preparation method and application thereof
The invention discloses a cluster phthalocyanine binary molecule photosensitizer as well as a preparation method and application thereof, wherein the cluster phthalocyanine binary molecule photosensitizer is formed by linking mercaptan-protected metal clusters and phthalocyanine molecules through ch...
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Main Authors | , , , |
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Format | Patent |
Language | Chinese English |
Published |
17.11.2020
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Subjects | |
Online Access | Get full text |
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Summary: | The invention discloses a cluster phthalocyanine binary molecule photosensitizer as well as a preparation method and application thereof, wherein the cluster phthalocyanine binary molecule photosensitizer is formed by linking mercaptan-protected metal clusters and phthalocyanine molecules through chemical bonds, and the structural formula of the cluster phthalocyanine binary molecule photosensitizer is shown in the specification. Metal atoms in the phthalocyanine cluster can generate a very strong heavy atom effect, rotary rail coupling in the phthalocyanine photosensitization process is enhanced, the ability of sensitizing phthalocyanine binary molecules in the cluster to generate singlet oxygen is improved, meanwhile, intersystem crossing between excited states is enhanced through rotaryrail coupling, and the anti-saturation absorption performance of phthalocyanine molecules is enhanced. According to the present invention, with the method, the good non-linear absorption effect can be provided for the picose |
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Bibliography: | Application Number: CN202010699481 |