High-mesopore-amount Y type zeolite and preparation method thereof

• Main Authors: SHEN BOJUN, YU QIANQIAN, KANG CHUNYAN, MI SHUO, LI CHENG, WANG WENNIAN, JIN WENLONG, GUO QIAOXIA, SHEN BAOHUA, SUN HOUXIANG, SHEN BAOJIAN, YUAN DELIN, LI LEI, ZHENG QINGQING, HAN HUAJUN
• Format: Patent
• Language: Chinese; English
• Published: 06.03.2018
• Subjects: CHEMISTRY; COMPOUNDS THEREOF; INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OFSOLID INORGANIC COMPOUNDS; INORGANIC CHEMISTRY; METALLURGY; NON-METALLIC ELEMENTS

The invention provides a preparation method of high-mesopore-amount Y type zeolite. The preparation method comprises: carrying out ammonium ion exchange treatment on Y type zeolite at a temperature of50-120 DEG C to obtain NH4Y zeolite; adding the NH4Y zeolite to a buffer solution with a concentration of 0.1-1 M, and beating to a slurry; slowly adding an ammonium fluorosilicate solution with a concentration of 0.01-1 M to the slurry in a dropwise manner, and stirring for 0.1-5 h at a temperature of 20-120 DEG C to obtain a crude product; directly carrying out alkali treatment on the crude product or carrying out alkali treatment after washing and drying, wherein the crude product is treated for 0.1-5 h at a temperature of 30-120 DEG C with an alkaline solution with a concentration of 0.01-3.0 M, and a mass ratio of the alkaline solution to the crude product is 1-50:1, preferably 5-40:1; and carrying out ammonium ion exchange on the obtained crude product at a temperature of 50-120 DEGC, calcining for 1-8 h at