Ferrocene based CNTs (carbon nano tubes) and preparation method thereof

The invention discloses a ferrocene based CNTs (carbon nano tubes) and a preparation method thereof. The preparation method comprises steps as follows: carboxylic CNTs are dispersed in anhydrous dichloromethane and subjected to ice-bath treatment to 0-5 DEG C under the inert gas shielding, oxalyl ch...

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Bibliographic Details
Main Authors CHANG XUEYI, CHENG ZHIYU, FAN HONGBO, QIU YONGFU
Format Patent
LanguageChinese
English
Published 16.01.2018
Subjects
BASIC ELECTRIC ELEMENTS
CAPACITORS
CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES ORLIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
CHEMISTRY
COMPOUNDS THEREOF
ELECTRICITY
GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS
INORGANIC CHEMISTRY
MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES
METALLURGY
NANOTECHNOLOGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION
SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE
TRANSPORTING
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Summary:The invention discloses a ferrocene based CNTs (carbon nano tubes) and a preparation method thereof. The preparation method comprises steps as follows: carboxylic CNTs are dispersed in anhydrous dichloromethane and subjected to ice-bath treatment to 0-5 DEG C under the inert gas shielding, oxalyl chloride is added, and a mixture reacts for 1 h at the temperature of 0-5 DEG C and then reacts for 10h at the room temperature; unreacted oxalyl chloride and anhydrous dichloromethane are removed through reduced-pressure suction, anhydrous aluminum chloride and anhydrous dichloromethane are added under the inert gas shielding, stirring is performed for 10 min, ice-bath treatment is performed until the temperature reaches 0-5 DEG C, ferrocene is added, and a mixture reacts for 1 h at the temperature of 0-5 DEG C, reacts for 4 h at the room temperature and then reacts for 2 h at the temperature of 40 DEG C; hydrochloric acid is dropwise added to stop the reaction, suction filtration is performed, a filter cake is alte
Bibliography:Application Number: CN20171878768