Ni-MOFs material as well as preparation method and application thereof

• Main Authors: WANG GUOZHONG, ZHANG HAIMIN, CHEN CHUN, ZHAO HUIJUN, SU YANPING
• Format: Patent
• Language: Chinese; English
• Published: 09.11.2016
• Subjects: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; COMPOSITIONS BASED THEREON; HETEROCYCLIC COMPOUNDS; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; THEIR PREPARATION OR CHEMICAL WORKING-UP; THEIR RELEVANT APPARATUS; TRANSPORTING

The invention discloses a Ni-MOFs material as well as a preparation method and application thereof. The microstructure of the Ni-MOFs material is the structure of a nanorod. The Ni-MOFs material is prepared by carrying out a reaction between a powder Ni-MOFs precursor, and anhydrous ethanol and deionized water of which the volume ratio is (2 to 27):3. After carbonization, the Ni-MOFs material can be used in a molecular catalysis hydrogenation reaction on a biomass platform. Not only does the Ni-MOFs material have a favorable catalytic performance in the molecular catalysis hydrogenation reaction on the biomass platform, but also the cost is low, the raw materials are rich, the preparation method is simple, and the suitability for large-scale production and application is high. 本发明公开了种Ni-MOFs材料及其制备方法与应用，该Ni-MOFs材料的微观形貌为纳米棒。该Ni-MOFs材料是通过将粉末Ni-MOFs前驱体与体积比为2～27:3的无水乙醇和去离子水进行反应制备而成。该Ni-MOFs材料碳化后可用于生物质平台分子催化加氢反应。本发明不仅在生物质平台分子催化加氢反应中具有良好的催化性能，而且成本低廉、原料丰富、制备方法简单，适合大规模生产应用。