Geopolymer composite material for 3D printing and preparation method and application thereof

• Main Authors: WANG BAOHUA, ZHANG TAO, HUO LIANG, LIAO JUAN, LIN XIQIANG, LI JINGFANG, JI WENZHAN, LI GUOYOU, ZHANG NAN
• Format: Patent
• Language: Chinese; English
• Published: 09.11.2016
• Subjects: ADDITIVE MANUFACTURING TECHNOLOGY; ADDITIVE MANUFACTURING, i.e. MANUFACTURING OFTHREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVEAGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING,STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING; ARTIFICIAL STONE; CEMENTS; CERAMICS; CHEMISTRY; CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS; CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATERTREATMENT OR WASTE MANAGEMENT; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS; CONCRETE; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; LIME, MAGNESIA; METALLURGY; PERFORMING OPERATIONS; REFRACTORIES; SLAG; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE; TRANSPORTING; TREATMENT OF NATURAL STONE

A geopolymer composite material for 3D printing and a preparation method and application thereof are disclosed. The geopolymer composite material comprises the following ingredients (by weight): 20-25% of water-quenched granulated blast furnace slag powder, 10-15% of ground steel slag, 0-5% of fly ash, 33-45% of tailings machine-made sand, 3-5% of a composite activator, 2.5-3% of a high-molecular polymer, 1-3% of a volume stabilizer, 1-2% of a thixotropic agent, 0.05-0.1% of an antifoaming agent and 13.9-12.45% of mixing water. The above ingredients are fully and uniformly stirred and then the mixture is subsequently pumped into a 3D printer for construction. The geopolymer composite material has good caking property, strong stability and has good pump-out morphology maintaining capability and bond property. Printed buildings have good morphology and volume stability, and houses and buildings have good overall stability and use security. 种3D打印用的地质聚合物复合材料及制备方法和用途，包括占组合物总重量20%～25%的高炉水淬矿渣粉，10%～15%的钢渣粉，0%～5%的粉煤灰，