Pre-heating decomposition method of producing sulfuric acid from phosphogypsum with co-production of cement

• Main Authors: TIAN JIAN, ZHU BINGBING
• Format: Patent
• Language: English
• Published: 09.12.2015
• Subjects: ARTIFICIAL STONE; CEMENTS; CERAMICS; CHEMISTRY; CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION ORPROCESSING OF GOODS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS; COMPOUNDS THEREOF; CONCRETE; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; INORGANIC CHEMISTRY; LIME, MAGNESIA; METALLURGY; NON-METALLIC ELEMENTS; REFRACTORIES; SLAG; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE; TREATMENT OF NATURAL STONE

The invention relates to the technical field of industrial production of sulfuric acid and cement, the field of industrial solid waste comprehensive utilization, and the field of environment protection and treatment, and particularly relates to a pre-heating decomposition method of producing sulfuric acid from phosphogypsum with co-production of cement. The method includes the steps of powder grinding of raw materials, multi-stage cyclic pre-heating, high-effective decomposition and kiln gas separation and purification. The method is used for preparing a cement raw material from the phosphogypsum subjected to pre-heating decomposition with clay, sand rock, coke and such auxiliary materials in the process of producing the sulfuric acid from the phosphogypsum with co-production of the cement. The method solves the problems that a pre-heating decomposition technology in the prior art is low in decomposition ratio of phosphogypsum, is low in productivity of sulfuric acid and clinker, is liable to cause crusting and blocking in a kiln and is high in production energy consumption, can reduce the decomposition efficiency of the phosphogypsum and accelerate escape of SO2, and further increase the productivity of the sulfuric acid and cement clinker. The pre-heating decomposition method of producing the sulfuric acid from the phosphogypsum with co-production of the cement can significantly reduce sintering temperature and energy consumption of the clinker, can reduce production cost of sulfuric and cement clinker, and can further increase comprehensive utilization rate of the phosphogypsum.