Preparation method of catalyst for improving yield of gasoline produced by catalytic cracking

• Main Authors: ZHAO XIAOZHENG, HU QINGXUN, WANG LIN, GAO XIONGHOU, LIU HONGHAI, XIONG XIAOYUN, ZHAO HONGJUAN, TIAN AIZHEN, WANG BAOJIE, ZHANG LI
• Format: Patent
• Language: English
• Published: 14.01.2015
• Subjects: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; CRACKING HYDROCARBON OILS; FUELS; LUBRICANTS; METALLURGY; MINERAL WAXES; PEAT; PERFORMING OPERATIONS; PETROLEUM, GAS OR COKE INDUSTRIES; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; TECHNICAL GASES CONTAINING CARBON MONOXIDE; THEIR RELEVANT APPARATUS; TRANSPORTING

The invention discloses a preparation method of a catalyst for improving the yield of gasoline produced by catalytic cracking. The preparation method comprises the following steps: with a mixture of kaolin and diatomite subjected to acid treatment as a raw material, adding chemical water, structural auxiliaries, a dispersing agent and/or a reinforcing agent into the mixture, and performing mixed pulping and spraying to obtain microspheres; roasting the sprayed microspheres, mixing the roasted microspheres with a guiding agent, sodium silicate and sodium hydroxide in a certain ratio, and performing a crystallization reaction under hydrothermal conditions, thereby obtaining a crystallization product with a pore structure and excellent abrasion resistance and with a 30%-60% NaY molecular sieve, wherein the crystallization product, namely the in-situ crystallized microspheres, can be taken as a precursor for preparing the catalytic cracking catalyst; and exchanging the in-situ crystallized microspheres with ammonium salt and rare earth to obtain the catalytic cracking catalyst for improving the yield of gasoline.