9,9<,>-bisanthracene derivative and preparation method thereof

The invention discloses a 9,9<,>- bisanthracene derivative having the following structural formula shown in the description, wherein, R is hydrogen, ethyl, propyl or 4-propyl cyclohexyl. The invention also discloses a preparation method of the 9,9<,>- bisanthracene derivative, comprising...

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Bibliographic Details
Main Authors SONG XINCHAO, MI YANGLI, WANG ZIJUN, AN YONG, XU MAOLIANG, TIAN JIE
Format Patent
LanguageChinese
English
Published 26.10.2011
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
ADHESIVES
CHEMISTRY
DYES
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC CHEMISTRY
PAINTS
POLISHES
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Summary:The invention discloses a 9,9<,>- bisanthracene derivative having the following structural formula shown in the description, wherein, R is hydrogen, ethyl, propyl or 4-propyl cyclohexyl. The invention also discloses a preparation method of the 9,9<,>- bisanthracene derivative, comprising the following steps: (1) adding magnesium powder, bromo aromatic hydrocarbon, tributyl borate in anhydrous tetrahydrofuran, for an ultrasonic radiation reaction for 1h at the temperature of 40 DEG C to obtain aryl boric acid, wherein, the molar ratio of bromo aromatic hydrocarbon to tributyl borate to magnesium powder is 1:2:3; and (2) adding 10,10<,>-dibromo-9,9<,>- bisanthracene, aryl boric acid and tetra(triphenylphosphine) palladium in a solution containing toluene, ethanol and sodium bicarbonate, wherein, the volume ratio of toluene to ethanol to sodium bicarbonate is 4:2:1, the molar ratio of 10,10<,>-dibromo-9,9<,>- bisanthracene to aryl boric acid is 2.5 :1, the amount of tetra(triphenylphosphine) palladium is 10% of
Bibliography:Application Number: CN20111107657