Thuyopsanone derived from thuiyopsene used - in fragrant comps

Thuyopsanone, a fragrant polycyclic ketone used in perfumed comps. esp. detergents, has the formula and is produced by oxidation of thuyopsene which has the formula by using: (a) a peracid e.g. peracetic in chloro-form at 0-50 degrees C; (b) oxidised derivs. of transition elements. pref. chromyl chl...

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Bibliographic Details
Main Authors OHLOFF,GUENTHER,DR, STRICKLER,HUGO,DR
Format Patent
LanguageEnglish
French
Published 15.06.1972
Edition1
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Summary:Thuyopsanone, a fragrant polycyclic ketone used in perfumed comps. esp. detergents, has the formula and is produced by oxidation of thuyopsene which has the formula by using: (a) a peracid e.g. peracetic in chloro-form at 0-50 degrees C; (b) oxidised derivs. of transition elements. pref. chromyl chloride in CCl4 at 10-20 degrees C, or (c) an oxidising gas, either pure. O2 or O2 mixed with eg N2, in combination with actinin irradiation e.g. Hg or Na vapour arc, and in the presence of an energy-transfer sensitiser e.g. rosin or pref. Rose-Bengale, pref. using a solvent such as methanol.
Bibliography:Application Number: CH19690003232