THERMALLY REARRANGED POLY(BENZOXAZOLE-IMIDE) COPOLYMER HAVING CROSS-LINKED STRUCTURE, GAS SEPARATION MEMBRANE COMPRISING SAME AND PREPARATION METHOD THEREFOR

• Main Authors: CALLE, MARIOLA, LEE, YOUNG MOO, LEE, JONG MYOUNG, JO, HYE JIN
• Format: Patent
• Language: English; French
• Published: 21.05.2015
• Subjects: CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; SEPARATION; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING

The present invention relates to: a preparation, by simple thermal treatment of a membrane prepared from an ortho-hydroxy polyimide copolymer having a carboxylic acid, of a thermally rearranged poly(benzoxazole-imide) membrane having a structure cross-linked by direct thermal cross-linking and simultaneous thermal rearrangement; a gas separation membrane comprising a thermally rearranged poly(benzoxazole-imide) copolymer having a structure, in which the content of a benzoxazole group in a copolymer chain is less than 80%, cross-linked by a transesterification cross-linking reaction of the ortho-hydroxy polyimide copolymer having a carboxylic acid with a diol-based compound and subsequent thermal rearrangement; and a preparation method therefor (however, a membrane for flue gas separation is excluded).