GAS CONVERSION USING HYDROGEN FROM SYNTHESIS GAS AND HYDROCONVERSION TAIL GAS

A gas conversion process including catalytic hydrocarbon synthesis from a synthesis gas comprising a mixture of H2 and CO, produces hydrogen from the synthesis gas and upgrades synthesized hydrocarbones by one or more hydroconversion operations which utilize this hydrogen. The hydroconversion also p...

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Bibliographic Details
Main Authors DEGEORGE, CHARLES WILLIAM, WITTENBRINK, ROBERT JAY, STARK, THOMAS MARSHALL
Format Patent
LanguageEnglish
French
Published 12.08.1999
Edition6
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
ORGANIC CHEMISTRY
PEAT
PETROLEUM, GAS OR COKE INDUSTRIES
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
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Summary:A gas conversion process including catalytic hydrocarbon synthesis from a synthesis gas comprising a mixture of H2 and CO, produces hydrogen from the synthesis gas and upgrades synthesized hydrocarbones by one or more hydroconversion operations which utilize this hydrogen. The hydroconversion also produces a hydrogen rich tail gas which is used in the process for at least one of (i) hydrocarbon synthesis catalyst rejuvenation, (ii) the hydrocarbon synthesis, and (iii) hydrogen production. In one embodiment the tail gas is used to hydrodesulfurize sulfur-containing hydrocarbon liquids recovered from the natural gas used to form the synthesis gas. The hydrogen production is accomplished by physical separation, such as PSA, with or without chemical means such as a water gas shift reaction.
Bibliography:Application Number: CA19992314332