Elementos compostos de materiais de pur, com superfìcies de camadas termoplásticas ou metálicas e um processo para produção dos mesmos

• Main Authors: PETER HAAS, DIRK WEGENER, REINER PAUL, DETLEF MIES
• Format: Patent
• Language: Portuguese
• Published: 27.09.2005
• Edition: 7
• Subjects: AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; LAYERED PRODUCTS; LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR; SHAPING OR JOINING OF PLASTICS; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS; WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL

"ELEMENTOS COMPOSTOS DE MATERIAIS DE PUR, COM SUPERFìCIES DE CAMADAS TERMOPLáSTICAS OU METáLICAS E UM PROCESSO PARA PRODUçãO DOS MESMOS". A invenção refere-se a elementos compostos, formados por uma camada externa (i), um material de PUR com aditivos de auto-separação como camada de suporte (ii) e, opcionalmente, uma camada interna decorativa (iii), a um processo para produção dos mesmos, bem como uso dos mesmos como componentes de carroceria. A composite element includes an outer layer containing a material from thermoplastics or metals; supporting layer comprising a reinforced polyurethane material; and optionally, a decorative inner layer. The supporting layer comprises a reinforced polyurethane material containing internal in-mold release additive(s) from polycondensate(s) of carboxylic acids, optionally carboxylic acid(s), and optionally ammonium salt(s) of carboxylic acid(s). A composite element comprises: (1) an outer layer containing a material from thermoplastics or metals; (2) supporting layer comprising a reinforced polyurethane (PU) material; and (3) optionally, a decorative inner layer. There is adhesion between layers (1-3). The reinforced PU material comprises internal in-mold release additive(s) comprising: (A) polycondensate(s) of carboxylic acids having a chain length of 8-40C, that are optionally mixed with dicarboxylic acid(s) and/or polyhydric alcohol(s); (B) optionally carboxylic acid(s) having a chain length of 8-40C; and (C) optionally ammonium salt(s) of carboxylic acid(s) having a chain length of 8-40C, and diamine(s) having primary amino group(s) and tertiary amino group(s). An independent claim is also included for a process for producing the composite elements, comprising: (1) introducing an outer layer into the bottom shell of a mold; (2) optionally, introducing a decorative material as inner layer into the top shell of the mold; (3) optionally, applying a fiber mat reinforcement into the outer layer, into the decorative material, or into the top shell of the mold; (4) applying a PU material into the outer layer or into the fiber mat reinforcement; (5) reacting the PU material in the mold; and (6) removing the resultant PU composite element from the mold. The PU material comprises polyisocyanate(s), isocyanate-reactive compound(s), optionally reinforcing material(s), catalyst(s), blowing agent(s), optionally, additive(s) and/or auxiliary substance(s), and in-mold release additive(s).