VERFAHREN ZUR HERSTELLUNG VON FLUORCHLORKOHLENWASSERSTOFF FREIEN, URETHANGRUPPEN ENTHALTENDEN FORMKÖRPERN MIT EINEM ZELLIGEN KERN UND EINER VERDICHTETEN RANDZONE

• Main Authors: HOELDERICH, WOLFGANG, DR, MUELLER, ULRICH, TINTELNOT, DIETER, SCHUSTER, LUDWIG, HORN, PETER, TADDEY, RUDOLF
• Format: Patent
• Language: German
• Published: 15.08.1996
• Edition: 6
• Subjects: ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS,e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES,DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; CONVEYING; GENERAL PROCESSES OF COMPOUNDING; HANDLING THIN OR FILAMENTARY MATERIAL; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PACKAGES; PACKAGING ELEMENTS; PACKING; PERFORMING OPERATIONS; STORING; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS; WORKING-UP

The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting   a) organic and/or modified organic polyisocyanates with   b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally   c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of   d) blowing agents,   e) catalysts,   f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and   g) auxiliaries, in a closed mould with compaction.