Electrochemical promoted CH bond chlorination of sulfoxonium ylides

[Display omitted] The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providi...

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Published inTetrahedron letters Vol. 114
Main Authors Zhang, Li-Ming, Fu, Zi-Hao, Yuan, Da-Fu, Guo, Ming-Zhong, Li, Ming, Wen, Li-Rong, Zhang, Lin-Bao
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 12.01.2023
Subjects
Chlorination
Electrochemistry
Sulfoxonium ylides
Chlorination
Electrochemistry
Sulfoxonium ylides
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Summary:[Display omitted] The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providing a green and mild route for the functionalization of sulfoxonium ylides.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2022.154244