Highly sensitive and quickly responding ultrasonically sprayed nanostructured SnO 2 thin films for hydrogen gas sensing

• Published in: Sensors and actuators. B, Chemical Vol. 143; no. 1; pp. 270 - 277
• Main Authors: Patil, L.A., Shinde, M.D., Bari, A.R., Deo, V.V.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 2009
• Subjects: High H 2 response; Microstructure; Nanocrystalline tin oxide; Ultrasonic spray pyrolysis; High H 2 response; Nanocrystalline tin oxide; Ultrasonic spray pyrolysis; Microstructure
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2009.09.048

Nanostructured SnO 2 thin films were prepared by ultrasonic spray pyrolysis technique. Aqueous solution (0.05 M) of SnCl 4 ·5H 2O in double distilled water was chosen as the starting solution for the preparation of the films. The stock solution was delivered to nozzle with constant and uniform flow rate of 70 ml/h by Syringe pump SK5001. Sono-tek spray nozzle, driven by ultrasonic frequency of 120 kHz, converts the solution into fine spray. The aerosol produced by nozzle was sprayed on glass substrate heated at 150 °C. The sensing performance of the films was tested for various gases such as LPG, hydrogen, ethanol, carbon dioxide and ammonia. The sensor (30 min) showed high gas response ( S = 3040 at 350 °C) on exposure of 1000 ppm of hydrogen and high selectivity against other gases. Its response time was short (2 s) and recovery was also fast (12 s). To understand reasons behind this uncommon gas-sensing performance of the films, their structural, microstructural, and optical properties were studied using X-ray diffraction, electron microscopy (SEM and TEM), and UV–vis spectroscopy, respectively. The results are interpreted.