Platinum nanoparticles on Al 2O 3: Correlation between the particle size and activity in total methane oxidation

• Published in: Journal of catalysis Vol. 268; no. 1; pp. 60 - 67
• Main Authors: Beck, Irene E., Bukhtiyarov, Valerii I., Pakharukov, Ilya Yu, Zaikovsky, Vladimir I., Kriventsov, Vladimir V., Parmon, Valentin N.
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 2009
• Subjects: Catalytic oxidation; Methane; Nanoparticles; Platinum; Size effect; Methane; Nanoparticles; Catalytic oxidation; Platinum; Size effect
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2009.09.001

Catalytic activity of size-controlled platinum nanoparticles supported on the acid-pretreated γ-alumina has been measured in complete methane oxidation under lean conditions. The strong size sensitivity was shown to originate from the size dependence of the apparent activation energy of the methane oxidation and/or oxidation state of platinum in the catalytically active nanoparticles. Catalytic activity of the size-controlled platinum nanoparticles supported on the acid-pretreated γ-alumina has been tested in complete methane oxidation under lean conditions. The mean sizes of platinum particles varied from 1.3 to 10 nm with the narrow size distribution (TEM data). It has been found that the reaction under study is strongly size sensitive. The size dependence of the specific catalytic activity is narrow and bell-shaped, with the maximum TOF value observed for the catalysts containing partially oxidized platinum with the mean particle sizes of about 2 nm. The observed strong size sensitivity is shown to originate from the size dependence of the apparent activation energy of the methane oxidation and/or the platinum oxidation state in the catalytically active nanoparticles.