Isothermal section of the Ni–Mn–In ternary system at 773K
•The isothermal section of the Ni–Mn–In ternary system at 773K was determined.•XRD, EPMA techniques were used.•13 single-phase, 27 two-phase and 14 three-phase regions were obtained.•7 binary compounds and 2 ternary compounds were confirmed.•The homogeneity ranges of the ternary compounds T1 and T2...
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Published in | Journal of alloys and compounds Vol. 622; pp. 149 - 154 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.02.2015
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Subjects | |
Online Access | Get full text |
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Summary: | •The isothermal section of the Ni–Mn–In ternary system at 773K was determined.•XRD, EPMA techniques were used.•13 single-phase, 27 two-phase and 14 three-phase regions were obtained.•7 binary compounds and 2 ternary compounds were confirmed.•The homogeneity ranges of the ternary compounds T1 and T2 were determined.
The isothermal section of the Ni–Mn–In ternary system at 773K was investigated and constructed using X-ray diffraction (XRD), and electron probe microanalysis (EPMA) techniques. The existence of 7 binary compounds and 2 ternary compounds was confirmed in the isothermal section. The six binary compounds Ni2In3 (Ni2Al3-type structure, space group P3¯m1), NiIn (CoSn-type structure, space group P6/mmc), Ni13In9 (Ni13Ga9-type structure, space group C2/m), Ni2In (Co1.75Ge-type structure, space group P63/mmc), Ni3In (Mg3Cd-type structure, space group P63/mmc) and Mn3In (Al4Cu9-type structure, space group P4¯3m) in the sub-binary systems Ni–In and Mn–In are stoichiometric compounds, the homogeneity ranges of which are negligible. While the five single phase regions in the Ni–Mn binary system show a more or less homogeneity ranges formed by replacement of Mn for Ni. The homogeneity ranges of the ternary compounds T1 (Ni2MnIn) and T2 (Mn3Ni2In) at 773K were determined. |
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ISSN: | 0925-8388 1873-4669 |
DOI: | 10.1016/j.jallcom.2014.09.219 |