Steam reforming of n -hexadecane using a Pd / ZrO 2 catalyst: Kinetics of catalyst deactivation

• Published in: International journal of hydrogen energy Vol. 32; no. 14; pp. 2868 - 2874
• Main Authors: Goud, Sandeep K., Whittenberger, William A., Chattopadhyay, Sudipta, Abraham, Martin A.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 2007
• Subjects: Catalytic reforming; Hydrogen; Metal foil catalyst; Methane steam reforming; Natural gas; Metal foil catalyst; Hydrogen; Catalytic reforming; Methane steam reforming; Natural gas
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2007.03.019

A systematic study of catalyst deactivation is required for the development of a coke resistant and sulfur tolerant catalyst for diesel fuel reforming systems to be used in conjunction with the solid oxide fuel cell (SOFC). In the present study, the performance of a Pd – ZrO 2 catalyst coated on a metal foil at various steam to carbon ratios (S/C), temperatures ( T ) and sulfur content (S) of the fuel were investigated for the steam reforming of n -hexadecane using a tubular reactor. Here n -hexadecane is used as the surrogate for diesel fuel. A decrease in time dependent hydrogen yield indicated catalyst deactivation, with the effects of reaction conditions on the rate of deactivation determined through a statistically designed experiment. A first-order kinetic model, with first-order deactivation rate, was used to obtain best fit values for the reaction rate constant ( k 0 ) and the deactivation rate constant ( k d ) as a function of S/C, temperature and sulfur loading. Palladium-catalyzed steam reforming of n -hexadecane was adequately modeled using first-order kinetics, the reaction rate was enhanced by increased temperatures and S/C ratios, but was decreased by the presence of sulfur. Catalyst deactivation was more rapid in the presence of sulfur, at low S/C ratios, and at lower temperatures.