Performance of a PEM water electrolysis cell using Ir x Ru y Ta z O 2 electrocatalysts for the oxygen evolution electrode

• Published in: International journal of hydrogen energy Vol. 32; no. 13; pp. 2320 - 2324
• Main Authors: Marshall, A.T., Sunde, S., Tsypkin, M., Tunold, R.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 2007
• Subjects: Electrocatalysis; Hydrogen production; Noble metal oxides; Oxygen evolution reaction; PEM water electrolysis; Electrocatalysis; Noble metal oxides; PEM water electrolysis; Oxygen evolution reaction; Hydrogen production
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2007.02.013

The performance of a PEM water electrolysis cell using Ir x Ru y Ta z O 2 anode electrocatalysts has been examined. The oxide powders were synthesised using an aqueous hydrolysis method, followed by thermal oxidation. With the cell operating at 80 ∘ C , the cell voltage at low current densities was dependant on the anode composition. At higher current densities the performance differences were less, most likely due to competing factors such as mass transport, electrical conductivity and surface area. A minimum in cell voltage was found at ruthenium contents around 40 mol%, which is explained as being the optimum between specific activity and active surface area. Overall the best cell voltage we achieved was 1.567 V at 1 A cm - 2 and 80 ∘ C , equating to an energy consumption of 3.75 kWh N m - 3 H 2 and an efficiency of 94% ( ε Δ H ) . This was achieved using a Ir 0.6 Ru 0.4 O 2 anode and 20% Pt/C cathode, with the total noble metal loading less than 2.04 mg cm - 2 .