Synthetic studies directed toward streptenol D: enantioselective preparation of the 3,5-diacetoxy-6 E,8 E-decadiene segment
The enantioselective preparation of 2-(3′ R,5′ R-diacetoxy-6 E,8 E-decadienyl)-1,3-dioxane, (+)- 13, is described. This synthesis of the skeleton of streptenol D utilizes the ability of a diene-complexed (tricarbonyl)iron unit to serve as a protecting and stereodirecting functionality.
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| Published in | Tetrahedron: asymmetry Vol. 9; no. 21; pp. 3781 - 3788 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
1998
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| Online Access | Get full text |
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| Summary: | The enantioselective preparation of 2-(3′
R,5′
R-diacetoxy-6
E,8
E-decadienyl)-1,3-dioxane, (+)-
13, is described. This synthesis of the skeleton of streptenol D utilizes the ability of a diene-complexed (tricarbonyl)iron unit to serve as a protecting and stereodirecting functionality. |
|---|---|
| ISSN: | 0957-4166 1362-511X |
| DOI: | 10.1016/S0957-4166(98)00388-7 |